Silica diagenesis in Eocene shallow-water platform carbonates, southern Pyrenees   总被引：1，自引：0，他引：1  

Jordi Giménez-Montsant  Francesc Calvet  & Maurice E. Tucker 《Sedimentology》1999,46(6):969-984

Spectacularly developed lower Eocene chert in the Corones platform carbonates of the Spanish Pyrenees is concentrated within a restricted, brackish-water, laminated ostracod-rich facies, which also contains abundant sponge spicules. The chert occurs as nodular, bedded and mottled varieties, and four petrographic types of quartz are developed: microquartz; length-fast (LF) chalcedony; megaquartz; and microspheres. δ¹⁸O values of chert range from 29·6‰ to 30·9‰ (SMOW), which correspond to a broad isotope rank common for biogenic and diagenetic replacement cherts. Calcian dolomite crystals with high Fe and Na are disseminated within the microquartz and LF-chalcedony, but are absent from the megaquartz and host carbonate. The chert is closely associated with desiccation cracks and with interstratal dewatering structures. Load casts are silicified, and laminae rich in sponge spicules are convoluted. Early cracks related to dewatering are filled by microquartz and quartz cements. Ostracod shells within chert are locally fractured; those in the host carbonate are commonly flattened. Late fractures are filled by LF-chalcedony and megaquartz. There is much evidence for the dissolution of sponge spicules and their calcitization in the carbonate host rock. Silica for the Corones cherts was derived from sponges during early diagenesis and shallow burial. Early mechanical compaction and sediment dewatering played a major role in sponge spicule dissolution, migration of silica-rich fluids and the consequent precipitation of chert. Quartz cements continued to be precipitated into the burial environment.  相似文献   

From London to Liverpool: Evidence for a Limehouse–Reid porcelain connection based on the analysis of sherds from the Brownlow Hill (ca. 1755–1767) factory site     

J. Victor Owen  Maurice Hillis 《Geoarchaeology》2003,18(8):851-882

The diversity of Brownlow Hill porcelains of the W^m Reid & Co. era is due to the remarkably wide range in the composition of their pastes and glazes and inferred firing conditions relative to the initial vitrification temperature. Sixteen of 21 analyzed sherds from the factory site are bone‐ash wares that display large variations in their bulk chemical composition. The remaining samples have silicious‐aluminous (akin to “stone china” sensu Richard Pococke in 1750) and silicious‐aluminous‐calcic (“S‐A‐C”) compositions that resemble Limehouse (London) and Pomona (Staffordshire) porcelains produced during the 1740s. The mineralogy of the Brownlow Hill S‐A‐C sherds suggests firing at a relatively high temperature (T_max approaching 1400°C, based on relations on the SiO₂‐Al₂O₃‐CaO phase diagram), thereby obscuring the identity of some of the ingredients (e.g., the source of CaO) used in their manufacture. Limehouse and Brownlow Hill may have been linked through the activities of William Ball, who is mentioned in connection with both factories, or indirectly via former Limehouse staff later employed at the Pomona factory, located not far from a W^m Reid & Co. branch factory in Shelton, Stoke‐on‐Trent. In terms of a time line, knowledge of these pastes appears to have spread first from London to Staffordshire, and then to Liverpool. © 2003 Wiley Periodicals, Inc.  相似文献   

Coleopteran evidence for a mosaic of environments at high altitude in the eastern Pyrénées,France, during the climatic transition between the Allerød and Younger Dryas     

Philippe Ponel  G. Russell Coope  Valrie Andrieu‐Ponel  Maurice Reille 《第四纪科学杂志》1999,14(2):169-174

Late‐glacial environmental and climatic implications are inferred from an insect fauna from organic sediments infilling a palaeochannel on the banks of the River Têt, eastern Pyrénées, France. A pine cone in association with the insect fauna has been radiocarbon dated to 10 920 ± 60 yr BP, namely close to the Allerød – Younger Dryas boundary. Two distinct insect associations appear to be recognisable here. One is an assemblage typical of the high altitude forest and a second is characteristic of an alpine grassland. The close coexistence of these two assemblages is attributed to the climatic cooling towards the start of the Younger Dryas Stadial, when the forest cover broke up into remnant patches interspersed by alpine grassland. It is suggested that in a region of such high relief a mosaic of habitats may have been caused by patchy differences in insolation aspect, especially during a period of climatic deterioration. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

A new approach to simulating disorder in crystals     

I. L. Jones  Volker Heine  Maurice Leslie  Geoffrey D. Price 《Physics and Chemistry of Minerals》1990,17(3):238-245

The technique of calculating lattice dissociation energies using static, minimum lattice energy, ionic models has been extended to allow for multiple occupancy of the ionic sites. A particular lattice site can have a fraction x of an ionic species A and a fraction y of an ionic species B, where the position of each can be relaxed separately along with the unit cell dimensions until an equilibrium is reached. Various degrees of long and short range order can be modelled. This technique has been applied to the mineral sillimanite, Al₂SiO₅, to calculate the effect on the lattice energy of (Al, Si) ordering over the tetrahedral sites. It is found using this method that (Al, Si) ordering with space group Pbmn stabilizes the material by 29.25 kcal/mol (Al^iv-O-Al^iv), with respect to the completely disordered material.  相似文献   

A review of dimethylsulfoxide in aquatic environments     

Peter A. Lee  Stephen J. de Mora  Maurice Levasseur 《大气与海洋》2013,51(4):439-456

Abstract

Dimethylsulfoxide (DMSO) is an ubiquitous, albeit poorly understood, component of the marine sulfur cycle. Conventionally, the accepted formation pathways are the photochemical and microbial oxidation of dimethylsulfide (DMS). The principal loss mechanism is thought to be via microbial transformation, either consumption or reduction to DMS. The interactions between DMSO and DMS are likely to be important in controlling sea surface concentrations of DMS, and thus DMSO could influence the role played by DMS in global climate regulation. This review examines current knowledge of the distribution of DMSO in aquatic environments and the possible link between DMSO, DMS and global climate control. Mechanisms for the formation and loss of DMSO are also considered in addition to some of the factors influencing these processes. The review also considers that DMSO may be biosynthesized by phytoplankton, representing a non‐DMS source for DMSO, and that DMSO can undergo photochemical oxidation, a potential loss mechanism for DMSO in the marine environment.  相似文献   

A note on the effects of virtual temperature: Research note     

Maurice Danard 《大气与海洋》2013,51(2):485-493

Abstract

The effects of virtual temperature on parcel buoyancy are investigated and the following results obtained. For descent or unsaturated ascent, the buoyancy acceleration is enhanced if the mixing ratio increases with pressure. However, for saturated ascent, the buoyancy acceleration is inhibited unless the lapse rate of mixing ratio exceeds a value slightly greater than that along a moist adiabat. This criterion is evaluated for several mean soundings. For the case of Oklahoma supercells, the mixing ratio lapse rate is clearly large enough. However, for other cases it often is not. Horizontal gradients in water vapour and condensed water can have a significant influence on the thermal wind.  相似文献   

Simplified analytical solution for point load acting behind a cantilever wall     

George Maurice Iskander 《国际地质力学数值与分析法杂志》2012,36(3):344-351

The analysis of earth pressure resulting from an applied point load behind a retaining wall is to be carried out in three dimensions as the earth pressure distribution varies both in vertical and horizontal directions. In this research, the semi‐empirical expressions developed by Terzaghi [Trans. ASCE 1954; 119 ] for earth pressure due to point load are integrated and a correction factor is introduced to develop equivalent equations for two‐dimensional analyses. A new parameter referred to as the design width, which is the horizontal distance retained by the individual vertical retaining element is introduced. The used procedure and the resulted equations are tested and verified by adopting different design width values covering the practical range. The resulted equations together with the semi‐empirical expressions of earth pressure due to line load developed by Terzaghi [Trans. ASCE 1954; 119 ] can be easily used for two‐dimensional analysis of the effect of point load. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Statistical inverse analysis based on genetic algorithm and principal component analysis: Applications to excavation problems and pressuremeter tests   总被引：1，自引：0，他引：1  

S. Levasseur  Y. Malecot  M. Boulon  E. Flavigny 《国际地质力学数值与分析法杂志》2010,34(5):471-491

This study concerns the identification of constitutive models from geotechnical measurements by inverse analysis. Soil parameters are identified from measured horizontal displacements of sheet pile walls and from a measured pressuremeter curve. An optimization method based on a genetic algorithm (GA) and a principal component analysis (PCA), developed and tested on synthetic data in a previous paper, is applied. These applications show that the conclusions deduced from synthetic problems can be extrapolated to real problems. The GA is a robust optimization method that is able to deal with the non‐uniqueness of the solution in identifying a set of solutions for a given uncertainty on the measurements. This set is then characterized by a PCA that gives a first‐order approximation of the solution as an ellipsoid. When the solution set is not too curved in the research space, this ellipsoid characterizes the soil properties considering the measured data and the tolerate margins for the response of the numerical model. Besides, optimizations from different measurements provide solution sets with a common area in the research space. This intersection gives a more relevant and accurate identification of parameters. Finally, we show that these identified parameters permit to reproduce geotechnical measurements not used in the identification process. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Enriched crustal and mantle components and the role of the lithosphere in generating Paleoproterozoic dyke swarms of the Ungava Peninsula,Canada     

Charles Maurice  Don Francis 《Lithos》2010,114(1-2):95-108

Paleoproterozoic mafic dyke swarms (2.5–2.0 Ga) of the Ungava Peninsula can be divided in three chemical groups. The main group has a wide range of Fe (10–18 wt.% Fe₂O₃) and Ti (0.8–2.0 wt.% TiO₂) contents, and the most magnesian samples have compositions consistent with melting of a fertile lherzolitic mantle at ~ 1.5 GPa. Dykes of a low-LREE (light rare earth element) subgroup (La/Yb ≤ 4) display decreasing Zr/Nb with increasing La/Yb ratios and positive εNd_2.0 Ga values (+ 3.9 to + 0.2) that trend from primitive mantle towards the composition of Paleoproterozoic alkaline rocks. In contrast, dykes of a high-LREE subgroup (La/Yb ≥4) display increasing Zr/Nb ratios and negative εNd_2.0 Ga values (? 2.3 to ? 6.4) that trend towards the composition of Archean crust. A low Fe–Ti group has low Fe (< 11 wt.% Fe₂O₃), Ti (< 0.8 wt.% TiO₂), high field strength elements (HFSE; < 6 ppm Nb) and heavy rare earth elements (HREE; < 2 ppm Yb) contents, but are enriched in large ion lithophile elements (LILE; K/Ti = 0.7–3) and LREE (La/Yb > 4). These dykes are interpreted as melts of a depleted harzburgitic mantle that has experienced metasomatic enrichment. A positive correlation of Zr/Nb ratio and La/Yb ratio, negative εNd_2.0 Ga values (? 14 to ? 6), and the presence of inherited Archean zircons further suggest the incorporation of a crustal component. A high Fe–Ti group has high Fe (> 14 wt.% Fe₂O₃) and Ti (> 1.4 wt.% TiO₂) contents, along with higher Na contents relative to the main group dykes. Dykes of a high-Al subgroup (> 12 wt.% Al₂O₃) share Fe contents, εNd_2.0 Ga values (? 2.3 to ? 3.4), La/Yb and Th/Nb ratios with Archean ferropicrites, and may represent evolved ferropicrite melts. A low-Al subgroup (< 12 wt.% Al₂O₃) has relatively lower Yb contents (< 2 ppm) and fractionated HREE patterns that indicate the presence of garnet in their melting residue. A comparison with ~ 5 GPa experimentally-derived melts suggests that these dykes may be derived from garnet-bearing pyroxenite or peridotite. The εNd_2.0 Ga values (? 0.3 to ? 2.0) of these dykes lie between the compositions of Archean granitoids and Paleoproterozoic alkaline rocks, signifying their petrogenesis involved both crustal and mantle components.Paleoproterozoic dykes containing a crustal component occur within, or close to, an isotopically enriched Archean terrane (T_DM 4.3–3.1 Ga), whereas dykes without this component occur in an isotopically juvenile terrane (T_DM < 3.1 Ga). The lack of a crustal component and the positive εNd_2.0 Ga values of dykes intruding the latter suggest that the crust they intruded was either too cold to be assimilated, or that its lower crust and/or lithosphere were Paleoproterozoic in age. In contrast, the ubiquitous presence of a crustal component and the diversity of mantle sources for dykes intruding the enriched terrane (lherzolite, harzburgite, pyroxenite) suggest a warmer crust with underlying heterogeneous lithospheric mantle.  相似文献   

Using 87Sr/86Sr, δ18O and δ2H isotopes along with major chemical composition to assess groundwater salinization in lower Shire valley,Malawi     

Maurice Monjerezi  Rolf D. Vogt  Per Aagaard  Asfaw Gebretsadik Gebru  John D.K. Saka 《Applied Geochemistry》2011,26(12):2201-2214

Groundwater resources in some parts of the lower section of Shire River valley, Malawi, are not useable for rural domestic water supply due to high salinity. In this study, a combined assessment of isotopic (⁸⁷Sr/⁸⁶Sr, δ¹⁸O and δ²H) and major ion composition was conducted in order to identify the hydro-geochemical evolution of the groundwater and thereby the causes of salinity. Three major end-members (representing fresh- and saline groundwater, and evaporated recharge) were identified based on major ion and isotopic composition. The saline groundwater is inferred to result from dissolution of evaporitic salts (halite) and the fresh groundwater shows influence of silicate weathering. Conservative mixing models show that brackish groundwater samples result from a three component mixture comprising the identified end-members. Hence their salinity is interpreted to result from mixing of fresh groundwater with evaporated recharge and saline groundwater. On the other hand, the groundwater with low TDS, found at some distance from areas of high salinity, is influenced by mixing of evaporated recharge and fresh groundwater only. Close to the Shire marshes, where there is shallow groundwater, composition of stable isotopes of water indicates that evaporation may also be an important factor.  相似文献